The uncertain location of electrons - George Zaidan and Charles Morton
电子位置的不确定性- 乔治·扎伊丹和查尔斯·莫顿
882,575 views ・ 2013-10-14
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翻译人员: xuanyu shi
校对人员: Qingqing Mao
00:06
You probably know that all stuff
is made up of atoms
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你或许知道所有东西都是由原子组成的。
00:10
and that an atom
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而原子本身
00:11
is a really, really, really,
really tiny particle.
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是一个非常非常非常小的粒子。
00:15
Every atom has a core,
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每个原子都有一个核,
00:16
which is made up of at least one
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由至少一个带正电的粒子组成,
00:18
positively charged particle
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这个正电粒子叫做质子,
00:19
called a proton,
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00:21
and in most cases,
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大多数情况下,
00:22
some number of neutral
particles called neutrons.
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还有一些中性粒子叫中子。
00:25
That core is surrounded
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原子核被称为电子的负电粒子包围。
00:26
by negatively charged
particles called electrons.
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00:30
The identity of an atom is determined
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一个原子的特性
00:32
only by the number
of protons in its nucleus.
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仅由原子核中质子的数量来确定。
00:36
Hydrogen is hydrogen because it
has just one proton,
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氢就是氢,因为它只有一个质子,
00:39
carbon is carbon because it has six,
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碳之所以是碳是因为它有6个质子,
00:41
gold is gold because it has 79,
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金之所以是金是因为它有79个质子,
00:43
and so on.
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诸如此类的还有很多。
00:45
Indulge me in a momentary tangent.
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请允许我讲会儿题外话。
00:47
How do we know about atomic structure?
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我们是如何知道原子的结构的呢?
00:49
We can't see protons,
neutrons, or electrons.
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我们又看不见质子、中子或电子。
00:53
So, we do a bunch of experiments
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所以,我们做了一堆实验,
00:55
and develop a model
for what we think is there.
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然后构造一个我们认为是对的模型。
00:58
Then we do some more experiments
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然后我们做更多的实验
00:59
and see if they agree with the model.
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来看看实际情况是否符合模型。
01:01
If they do, great.
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如果是,那最好了。
01:02
If they don't, it might
be time for a new model.
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如果不是, 那就是时候来建一个新模型了。
01:05
We've had lots of very
different models for atoms
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自公元前400年的德谟克利特以来,
01:08
since Democritus in 400 BC,
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我们有很多不同的原子模型,
01:10
and there will almost certainly
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而且将来肯定会有更多的模型出现。
01:12
be many more to come.
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01:13
Okay, tangent over.
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好了,题外话结束。
01:15
The cores of atoms tend to stick together,
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原子的核心往往是粘在一起的,
01:18
but electrons are free to move,
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但电子可以自由移动,
01:20
and this is why chemists love electrons.
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这就是化学家爱电子的原因了。
01:22
If we could marry them,
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如果我们可以和它们结婚,
01:24
we probably would.
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我想我们会的。
01:25
But electrons are weird.
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但是电子很奇怪。
01:26
They appear to behave either as particles,
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它们的表现既像是粒子,
01:29
like little baseballs,
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像是小棒球,
也像是波浪,水的波浪。
01:31
or as waves, like water waves,
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01:33
depending on the experiment
that we perform.
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它们在不同的实验中有着不同的表现。
01:36
One of the weirdest things about electrons
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关于电子最奇怪的事情是
01:38
is that we can't exactly
say where they are.
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我们无法知道它们的确切位置。
01:40
It's not that we don't have the equipment,
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这并不是说我们没有合适的设备,
01:42
it's that this uncertainty
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而是这种不确定性
01:44
is part of our model of the electron.
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也是我们的电子模型的一部分。
01:46
So, we can't pinpoint them, fine.
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所以,好吧,我们不能精确定位它们。
01:49
But we can say
there's a certain probability
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但我们可以说,
01:51
of finding an electron in a given space
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在原子核周围的一个给定区域中
01:53
around the nucleus.
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找到一个电子的几率是多少。
01:55
And that means that we can
ask the following question:
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这就意味着我们可以问以下的问题:
01:58
If we drew a shape around the nucleus
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如果我们绕原子核画一个形状,
02:00
such that we would be 95% sure
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使得我们将有95%的把握
02:02
of finding a given electron
within that shape,
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在这个形状中找到一个给定的电子,
02:05
what would it look like?
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它会是什么样的?
02:08
Here are a few of these shapes.
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这里有几个形状,
02:10
Chemists call them orbitals,
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化学家们称之为轨道。
02:12
and what each one looks like
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决定每个轨道的形状的因素之一
02:13
depends on, among other things,
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02:15
how much energy it has.
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是它们所拥有能量的多少。
02:17
The more energy an orbital has,
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一个轨道拥有的能量越多,
02:19
the farther most of its density is
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那么它的主要部分就离原子核越远。
02:21
from the nucleus.
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02:22
By they way, why did we pick 95%
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顺便提一下,
为什么我们选择95%的把握而不是100%?
02:25
and not 100%?
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02:26
Well, that's another quirk
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好吧,那是我们电子模型另一个比较特殊的地方。
02:28
of our model of the electron.
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从离开原子核的一定距离开始,
02:30
Past a certain distance from the nucleus,
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02:32
the probability of finding an electron
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发现电子的几率
02:34
starts to decrease
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开始随着距离下降,
02:35
more or less exponentially,
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差不多呈现指数衰减,
02:37
which means that while it
will approach zero,
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这就意味着几率会越来越接近零,
02:40
it'll never actually hit zero.
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但事实上永远不会达到零。
02:43
So, in every atom,
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所以,每一个原子中,
02:44
there is some small,
but non-zero, probability
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总有一些很小,但是非零的可能性,
02:47
that for a very, very
short period of time,
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在很短很短的一段时间里
02:50
one of its electrons
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其中一个电子
02:51
is at the other end of the known universe.
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正位于宇宙的另一端。
02:55
But mostly electrons stay
close to their nucleus
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但是大部分时间电子都距离原子核很近,
02:58
as clouds of negative charged density
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呈现为带负电的电子云,
03:00
that shift and move with time.
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电子云会随着时间改变位置。
03:02
How electrons from one atom
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一个原子的电子如何和
03:04
interact with electrons from another
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另一个原子的电子互相作用
03:06
determines almost everything.
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几乎决定了一切。
03:08
Atoms can give up their electrons,
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原子可以放弃自己的电子,
03:10
surrendering them to other atoms,
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把它们给其他原子,
03:12
or they can share electrons.
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或者与其他原子共享电子。
03:15
And the dynamics of this social network
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而这个社交网络的动态
03:17
are what make chemistry interesting.
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使化学变得有趣。
03:19
From plain old rocks
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从普通的旧石头
03:20
to the beautiful complexity of life,
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到美好而复杂的生命,
03:22
the nature of everything we see,
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自然界中一切我们可以看到的,
03:24
hear,
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听到的,闻到的
03:25
smell, taste, touch, and even feel
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品尝到的,
触摸到的,
03:28
is determined at the atomic level.
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都是在原子层面决定的。
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