Is fire a solid, a liquid, or a gas? - Elizabeth Cox

Sitting around a campfire, you can feel its heat,

smell the woody smoke, and hear it crackle.

If you get too close,

it burns your eyes and stings your nostrils.

You could stare at the bright flames forever

as they twist and flicker in endless incarnations.

But what exactly are you looking at?

The flames are obviously not solid,

nor are they liquid.

Mingling with the air, they’re more like a gas,

but more visible--and more fleeting.

And on a scientific level, fire differs from gas

because gases can exist in the same state indefinitely

while fires always burn out eventually.

One misconception is that fire is a plasma,

the fourth state of matter in which atoms

are stripped of their electrons.

Like fire and unlike the other kinds of matter,

plasmas don’t exist in a stable state on earth.

They only form when gas is exposed to an electric field or superheated

to temperatures of thousands or tens of thousands of degrees.

By contrast, fuels like wood and paper burn

at a few hundred degrees —far below the

threshold of what's usually considered a plasma.

So if fire isn’t a solid, liquid, gas,

or a plasma, what does that leave?

It turns out fire isn’t actually matter at all.

Instead, it’s our sensory experience of a chemical reaction called combustion.

In a way, fire is like the leaves changing color in fall,

the smell of fruit as it ripens,

or a firefly’s blinking light.

All of these are sensory clues that a

chemical reaction is taking place.

What differs about fire is that it engages a lot of

our senses at the same time, creating the kind of vivid

experience we expect to come from a physical thing.

Combustion creates that sensory experience

using fuel, heat, and oxygen.

In a campfire, when the logs are heated to their ignition temperature,

the walls of their cells decompose,

releasing sugars and other molecules into the air.

These molecules then react with airborne oxygen

to create carbon dioxide and water.

At the same time, any trapped water in the logs

vaporizes, expands, ruptures the wood around it,

and escapes with a satisfying crackle.

As the fire heats up, the carbon dioxide and water vapor

created by combustion expand.

Now that they’re less dense, they rise in a thinning column.

Gravity causes this expansion and rising, which gives

flames their characteristic taper.

Without gravity, molecules don’t separate

by density and the flames have a totally different shape.

We can see all of this because combustion

also generates light.

Molecules emit light when heated,

and the color of the light depends

on the temperature of the molecules.

The hottest flames are white or blue.

The type of molecules in a fire can

also influence flame color.

For instance, any unreacted carbon atoms from the logs

form little clumps of soot that rise

into the flames and emit the yellow-orange

light we associate with a campfire.

Substances like copper, calcium chloride,

and potassium chloride can add their

own characteristic hues to the mix.

Besides colorful flames,

fire also continues to generate heat as it burns.

This heat sustains the flames by keeping

the fuel at or above ignition temperature.

Eventually, though, even the hottest fires

run out of fuel or oxygen.

Then, those twisting flames give a final hiss

and disappear with a wisp of smoke

as if they were never there at all.