Why doesn’t anything stick to Teflon? - Ashwini Bharathula

3,096,866 views ・ 2016-12-13

TED-Ed


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翻译人员: Cissy Yun 校对人员: Junkai Fu
00:08
Nothing stuck to Mafia boss John Gotti
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黑手党老大John Gotti可以做到 与什么犯罪事件都沾不上边
00:11
who evaded justice for years by bribing and threatening jurors and witnesses.
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多年,他靠威胁听审团和目击者 来逃离法网
00:16
That earned him the name the Teflon Don
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这还使他多了个外号 特氟龙先生
00:19
after one of the slipperiest materials on Earth.
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这个外号来源于世界上最滑的物质
00:22
Teflon was in the spacesuits the Apollo crew wore for the moon landing,
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特氟龙本用于阿波罗号的宇航员登月穿的宇航服
00:26
in pipes and valves used in the Manhattan Project,
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用于曼哈顿计划(原子弹制造)的管道中
00:29
and maybe in your kitchen as the nonstick coating on frying pans and cookie sheets.
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还存在于你厨房中的不粘锅和饼干纸上
00:35
So what is this slippery solid, and why doesn't anything stick to it?
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所以这种滑滑的固体到底是什么呢? 而为什么其他东西都粘不上去呢?
00:39
Teflon is a brand name for polytetrafluoroethylene,
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特氟龙的另一个名字是 聚四氟乙烯
00:43
or PTFE.
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或称PTFE
00:45
It was stumbled upon accidentally in 1938 by a 27-year-old American chemist
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它的出现全因为发生在1938年 27岁的美国化学家造成的一场意外
00:51
named Roy Plunkett
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他的名字叫做 Roy Plunkett
00:52
while he was trying to develop a non-toxic refrigerant fluid for DuPont,
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当时他正在为杜邦公司 开发一种无毒制冷剂
00:57
a chemicals company.
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那是一家化学公司
00:59
The strange, white substance that formed inside his lab canister
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这种奇怪的,白色的物质 在他的实验室罐中出现
01:02
was chemically inert,
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是惰性的化学物质
01:04
meaning it wouldn't react with other substances.
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就是它不会与其他物质产生反应
01:07
It also had an extremely low coefficient of friction,
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它还有一个非常低的摩擦系数,
01:10
making other materials slide right off it.
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让其他物质都从它旁边滑走
01:13
Teflon's properties make it perfect when you need something slippery,
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特氟龙的特质帮助了 当人们需要滑滑的东西
01:17
chemical resistant,
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耐化学性
01:18
or waterproof,
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或是防水性
01:20
which means it has a lot of applications.
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这代表了它有许多可用之地
01:22
It can be found all over the place,
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可以在很多地方找到它的身影
01:24
as a coating on raincoats,
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雨衣上的防水层
01:26
industrial ball bearings,
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工业球支座
01:28
artificial joints,
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人工关节
01:29
circuit boards,
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电线板
01:30
and even the Rocky Mountains-themed roof of the Denver International Airport.
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甚至是丹佛国际机场的 落基山脉主题屋顶上
01:35
The incredible properties of PTFE come from its molecular structure.
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PTFE的特质是因为 它的分子结构
01:40
It's a polymer,
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它是一个聚合物
01:41
meaning it's made of long chains of repeating units of atoms strung together.
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说明它是由一串相同的原子聚集
01:45
A PTFE chain has a backbone of carbon atoms,
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一个PTFE链有碳原子的主链
01:49
each of which is attached to two fluorines.
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每一个碳原子还连接两个氟原子
01:52
The fluorine atoms surround the carbon like armor,
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围绕着碳原子的氟原子就像是盔甲一样
01:55
spiraling around the chain,
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在链边旋绕
01:57
and the bond between carbon and fluorine is incredibly tight.
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碳原子和氟原子之间的纽带很紧
02:00
Like a couple that ignores everyone except each other,
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就像一对无视他人的情侣
02:03
carbon and fluorine interact so strongly
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碳原子和氟原子强烈地相互作用
02:06
that the normal, intermolecular forces that help substances stick to each other
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造成正常的,作用于分子间的力 来帮助物质黏在一起
02:10
don't stand a chance.
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根本不起作用
02:12
Even the famously adhesive feet of geckos usually can't get a grip.
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就连以有着胶脚的壁虎 都粘不上去
02:16
But wait!
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但,等等!
02:18
If PTFE doesn't stick to anything,
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如果PTFE粘不上任何东西
02:20
how can it be so firmly attached to something like a pan?
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它们是怎么粘到铁锅上形成不粘锅的呢?
02:24
One method involves sandblasting the pan
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一种方式是把铁锅喷砂
02:27
or etching it with chemicals to make it rough.
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或用化学物质腐蚀使之粗糙
02:30
Then, a special primer is applied, which acts like glue.
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而后, 一种特殊的底漆会被涂上 作用为一种胶水
02:34
Its exact composition is a trade secret guarded by each manufacturer.
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它的主要成分是每个制造商保存的商业机密
02:39
The pan is sprayed with liquid PTFE
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铁锅会被喷上液体的PTFE
02:42
and heated to around 800 degrees Fahrenheit.
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并在800华氏温度下加热
02:45
The layers then solidify into a smooth, slick coating.
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然后这层会固化成光滑的涂层
02:49
When you later cook eggs in this PTFE-coated pan,
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当而后你在PTFE层上面煎鸡蛋时
02:52
the extra tight carbon-fluorine bonds
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其中的紧密的碳氟链
02:55
just ignore the water and fat and protein molecules in the eggs.
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会无视鸡蛋中的 水,脂肪和蛋白质分子
02:58
Without those interactions,
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没有了这些反应
03:00
the food just slides around without sticking.
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食物就不会黏在锅子上
03:03
You might wonder if it's safe to cook in a PTFE-coated pan.
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你也许会担心是否用有PTFE层的锅 烧饭会不会不安全
03:07
The answer is yes, if you're careful.
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答案是,如果你当心的话,是非常安全的
03:10
PTFE is stable at moderate temperatures, like you'd use to cook eggs or fish,
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PTFE在中等温度下是稳定的 就像你在炒鸡蛋或是做鱼时
03:16
but above 500 degrees Fahrenheit, it starts to degrade,
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但是,达到500华氏温度以上 PTFE会开始降解
03:19
and heating it further releases fumes that can make you feel sick.
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而过度得加热 会发出令人不适的烟味
03:23
An empty pan can reach 500 degrees fast over high heat,
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一个空锅能在高温下快速达到500度
03:27
but most kitchens are ventilated well enough to dissipate the fumes.
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但是大多的厨房 都有通风渠道来驱散烟雾
03:31
People used to also think that accidentally consuming PTFE
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人们过去也认为意外摄入PTFE
03:35
that flaked off a scratched pan was bad for you,
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从锅中剥落的PTFE层
03:38
but the current consensus is that it's harmless.
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但目前的共识是,它是无害的
03:41
Because PTFE doesn't interact with other chemicals very well,
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因为PTFE并不会与其他化学物质 产生反应
03:45
it isn't thought to break down inside your body.
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它不会在你身体中分解
03:48
Whether it's safe to manufacture Teflon is another story.
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然而,特氟龙的生产是否安全就是另当别论了
03:51
DuPont and its spin-off company Chemours
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杜邦和它的附属公司Chemourus
03:54
now face lawsuits worth millions of dollars.
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现在面临价值数百万美元的诉讼
03:57
They've been accused of polluting the environment for decades
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他们被起诉几十年来污染环境
04:00
and exposing employees and local communities
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并将员工和当地社区暴露在
04:02
to health risks associated with a toxic chemical called PFOA.
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与PFOA一种有毒的化学物质接触 健康危险中
04:07
That chemical was involved in manufacturing Teflon.
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在生产特氟龙是 这种化学物质会被用到
04:11
As for John Gotti,
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再说到John Gotti
04:12
in 1992, the Mob boss was finally convicted of five counts of murder,
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在1992年,这位黑手党老大 最终被判有五项谋杀罪
04:17
among other charges.
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和其他的一些指控
04:19
That prompted the head of the FBI office in New York City to announce,
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所以FBI在纽约的主任说
04:22
"The Teflon is gone.
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“特氟龙先生已经捉拿归案”
04:24
The don is covered in Velcro, and all the charges stuck."
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“这位先生全身都有魔术贴, 所有的指控都会黏上去。”
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