The most colorful gemstones on Earth - Jeff Dekofsky

648,460 views ・ 2020-12-03

TED-Ed


Please double-click on the English subtitles below to play the video.

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On an auspicious day in November of 1986,
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5 Australian miners climbed Lunatic Hill—
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so named for the mental state anyone would be in to dig there.
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While their competitors searched for opals at a depth of 2 to 5 meters,
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the Lunatic Hill Syndicate bored 20 meters into the earth.
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And for their audacity, the earth rewarded them
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with a fist-sized, record breaking opal.
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They named it the Halley’s Comet opal,
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after the much larger rocky, icy body flying by the earth at that time.
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The Halley’s Comet opal is a marvel, but its uniqueness is, paradoxically,
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the most usual thing about it.
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While diamonds, rubies, emeralds, and other precious stones
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are often indistinguishably similar,
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no two opals look the same,
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thanks to a characteristic called "play of color."
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This shimmering, dazzling, dancing display of light
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comes about from a confluence of chemistry, geology, and optics
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that define opals from their earliest moments, deep underground.
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It’s there that an opal begins its life as something surprisingly abundant: water.
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Trickling down through gaps in soil and rock,
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water flows through sandstone, limestone, and basalt,
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picking up a microscopic compound called silicon dioxide.
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This silica-enriched water enters the voids inside pieces of volcanic rock,
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prehistoric river beds, wood and even the bones of ancient creatures.
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Gradually, the water starts to evaporate,
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and the silica-solution begins forming a gel,
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within which millions of silica spheres form layer by layer
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as a series of concentric shells.
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The gel ultimately hardens into a glass-like material,
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and the spheres settle into a lattice structure.
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The vast majority of the time, this structure is haphazard,
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resulting in common, or potch, opals with unremarkable exteriors.
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The tiny, mesmerizing percentage we call precious opals
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have regions where silica beads of uniform size form orderly arrays.
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So why do those structures produce such vibrant displays?
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The answer lies in a principle of wave physics called interference.
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For the sake of simplicity,
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let’s look at what happens when a single color of light—
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green, with a wavelength of 500 nanometers— hits a precious opal.
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The green light will scatter throughout the gemstone
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and reflect back with varying intensities—
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from most angles suffused, from some entirely dimmed,
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and others dazzlingly bright.
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What’s happening is, some of the green light reflects off of the top layer.
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Some reflects off of the layer below that.
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And so on.
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When the additional distance it travels from one layer to the next, and back,
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is a multiple of the wavelength— such as 500 or 1000 extra nanometers—
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the crests and valleys of the waves match each other.
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This phenomenon is called constructive interference,
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and it amplifies the wave, producing a brighter color.
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So if you position your eye at the correct angle,
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the green light reflecting from many layers adds together.
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Shift the angle just a bit,
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and you change the distance the light travels between layers.
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Change it enough, and you’ll reach a point where the crests match the valleys,
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making the waves cancel each other out— that’s destructive interference.
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Different colors have different wavelengths,
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which translates to varying distances they have to travel
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to constructively interfere.
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That’s why colors roughly correspond to silica bead sizes.
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The spaces between 210 nanometer beads are just right to amplify blue light.
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For red light, with its long wavelengths,
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the silica beads must be close to 300 nanometers.
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Those take a very long time to form, and because of that,
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red is the rarest opal color.
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The differences in the arrangements of the gel lattices
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within a particular stone result in a wide range of color patterns—
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everything from broad flash to pin-fire to the ultra-rare harlequin.
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The circumstances that lead to the formation of precious opal
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are so uncommon that they only occur in a handful of places.
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About 95% come from Australia,
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where an ancient inland sea created the perfect conditions.
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It was there that the Halley’s Comet opal formed some 100 million years ago.
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Which raises the question: in the next 100 million years,
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silica-rich water will percolate through the nooks and crannies
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of some of the discarded artifacts of human civilization.
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What opalescent plays of light will one day radiate
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from the things we forget in the darkness?
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