How do crystals work? - Graham Baird

3,435,621 views ・ 2019-06-18

TED-Ed


Please double-click on the English subtitles below to play the video.

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Deep beneath the geysers and hot springs of Yellowstone Caldera
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lies a magma chamber produced by a hot spot in the earth’s mantle.
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As the magma moves towards the Earth’s surface,
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it crystallizes to form young, hot igneous rocks.
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The heat from these rocks drives groundwater towards the surface.
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As the water cools, ions precipitate out as mineral crystals,
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including quartz crystals from silicon and oxygen,
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feldspar from potassium, aluminum, silicon, and oxygen,
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galena from lead and sulfur.
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Many of these crystals have signature shapes—
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take this cascade of pointed quartz, or this pile of galena cubes.
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But what causes them to grow into these shapes again and again?
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Part of the answer lies in their atoms.
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Every crystal’s atoms are arranged in a highly organized, repeating pattern.
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This pattern is the defining feature of a crystal,
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and isn’t restricted to minerals—
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sand, ice, sugar, chocolate, ceramics, metals, DNA,
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and even some liquids have crystalline structures.
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Each crystalline material’s atomic arrangement
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falls into one of six different families:
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cubic, tetragonal, orthorhombic, monoclinic, triclinic, and hexagonal.
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Given the appropriate conditions,
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crystals will grow into geometric shapes
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that reflect the arrangement of their atoms.
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Take galena, which has a cubic structure composed of lead and sulfur atoms.
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The relatively large lead atoms
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are arranged in a three-dimensional grid 90 degrees from one another,
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while the relatively small sulfur atoms fit neatly between them.
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As the crystal grows, locations like these attract sulfur atoms,
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while lead will tend to bond to these places.
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Eventually, they will complete the grid of bonded atoms.
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This means the 90 degree grid pattern of galena’s crystalline structure
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is reflected in the visible shape of the crystal.
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Quartz, meanwhile, has a hexagonal crystalline structure.
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This means that on one plane its atoms are arranged in hexagons.
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In three dimensions, these hexagons are composed of many interlocking pyramids
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made up of one silicon atom and four oxygen atoms.
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So the signature shape of a quartz crystal
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is a six-sided column with pointed tips.
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Depending on environmental conditions,
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most crystals have the potential to form multiple geometric shapes.
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For example, diamonds, which form deep in the Earth’s mantle,
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have a cubic crystalline structure and can grow into either cubes or octahedrons.
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Which shape a particular diamond grows into
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depends on the conditions where it grows,
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including pressure, temperature, and chemical environment.
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While we can’t directly observe growth conditions in the mantle,
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laboratory experiments have shown some evidence
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that diamonds tend to grow into cubes at lower temperatures
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and octahedrons at higher temperatures.
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Trace amounts of water, silicon, germanium, or magnesium
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might also influence a diamond’s shape.
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And diamonds never naturally grow into the shapes found in jewelry—
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those diamonds have been cut to showcase sparkle and clarity.
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Environmental conditions can also influence whether crystals form at all.
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Glass is made of melted quartz sand,
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but it isn’t crystalline.
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That’s because glass cools relatively quickly,
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and the atoms do not have time to arrange themselves
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into the ordered structure of a quartz crystal.
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Instead, the random arrangement of the atoms in the melted glass
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is locked in upon cooling.
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Many crystals don’t form geometric shapes
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because they grow in extremely close quarters with other crystals.
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Rocks like granite are full of crystals,
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but none have recognizable shapes.
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As magma cools and solidifies,
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many minerals within it crystallize at the same time and quickly run out of space.
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And certain crystals, like turquoise,
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don’t grow into any discernible geometric shape in most environmental conditions,
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even given adequate space.
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Every crystal’s atomic structure has unique properties,
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and while these properties may not have any bearing on human emotional needs,
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they do have powerful applications in materials science and medicine.
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